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Journal of Engineering Research. 2025; 4: (4) ; 10.12208/j.jer.20250195 .

Regulation of crystallization behavior of polyethylene terephthalate (PET) and its effect on mechanical properties
聚对苯二甲酸乙二醇酯(PET)结晶行为调控及其对力学性能的影响

作者: 熊磊 *

欧绿保龙一新材料(江西)有限公司 江西鹰潭

*通讯作者: 熊磊,单位:欧绿保龙一新材料(江西)有限公司 江西鹰潭;

引用本文: 熊磊 聚对苯二甲酸乙二醇酯(PET)结晶行为调控及其对力学性能的影响[J]. 工程学研究, 2025; 4: (4) : 153-155.
Published: 2025/4/10 14:00:43

摘要

聚对苯二甲酸乙二醇酯(PET)结晶行为对其力学性能具有关键影响。探究结晶行为调控手段与力学性能变化规律,有助于拓展 PET 应用领域。研究发现,温度、成核剂添加等因素显著影响 PET 结晶行为。高温促进结晶完善度提升,但过高温度会导致分子链降解;成核剂可加快结晶速率,细化晶粒。结晶度提高能增强 PET 拉伸强度与模量,然而过高结晶度会降低材料韧性。深入理解二者关系,为 PET 性能优化提供理论依据。

关键词: 聚对苯二甲酸乙二醇酯;结晶行为;力学性能;调控因素;晶粒结构

Abstract

The crystallization behavior of polyethylene terephthalate (PET) significantly influences its mechanical properties. Investigating the methods to control crystallization and the patterns of mechanical property changes can help expand the application areas of PET. Research has found that factors such as temperature and the addition of nucleating agents significantly affect PET crystallization behavior. High temperatures enhance crystallization perfection, but excessively high temperatures can lead to molecular chain degradation; nucleating agents can accelerate crystallization rates and refine grains. Increased crystallinity enhances the tensile strength and modulus of PET, yet excessive crystallinity reduces material toughness. A deeper understanding of these relationships provides a theoretical basis for optimizing PET performance.

Key words: Polyethylene terephthalate; Crystallization behavior; Mechanical properties; Regulation factors; Grain structure

参考文献 References

[1] 王敬慧,孙海波,李博思.基于结晶器内宏观传输行为调控的铸坯皮下负偏析控制研究[J].黑龙江科学,2025, 16(04):56-59+64.

[2] 罗天,洪楚玲,申佳帆,等.结晶行为调控电纺纳米纤维物理性能研究进展[J].纺织高校基础科学学报,2025, 38(01):39-52.

[3] 沈赢洲,刘磊,种锦轩,等.超分子助剂对间规聚苯乙烯构象和结晶行为的调控[J].中国塑料,2024,38(12):1-7.

[4] 林福华,荀慧霞,张秀芝.不同金属离子复配的有机磷酸盐成核剂调控PP结晶行为和应用性能[J].工程塑料应用,2024,52(10):151-158.

[5] 龚宁,韩鑫,司晓雯,等.PE-g-PMMA的结晶驱动溶液自组装行为——侧链对片晶形貌的调控[J].宁波大学学报(理工版),2024,37(03):113-120.

[6] 缪璐璐,董正梅,谢国炎,等.PHBV结晶行为调控与相变机理的研究进展[J].现代纺织技术,2023,31(04):119-129.

[7] 吴晗,杨顺燚,蒋妮,等.聚苯乙烯嵌段对左旋聚乳酸/聚苯乙烯-b-右旋聚乳酸立构复合晶结晶行为的调控[J].高分子学报,2023,54(05):631-642.

[8] 张露,张晴.油脂结晶改良剂对底物油脂结晶行为的调控及其作用机制的研究进展[J].中国油脂,2023,48(08):23-29+33.