Journal of Chemistry and Chemical Research
Journal of Chemistry and Chemical Research. 2024; 4: (2) ; 10.12208/j.jccr.20240013 .
总浏览量: 46
南通大学 江苏南通
*通讯作者: 张华,单位:南通大学 江苏南通;
本文系统综述了面向碳中和目标的高效催化剂设计及应用进展。催化剂作为加速化学反应的关键媒介,在二氧化碳还原(CO22RR)、氢能源生产等核心领域发挥核心作用,通过优化活性、选择性、稳定性及耐久性,显著降低能源消耗与碳排放。金属基催化剂(如铂、铜合金)通过纳米结构调控与复合设计提升性能,而非金属基催化剂(如氮掺杂碳材料)及生物催化剂则展现出低成本与环境友好优势。未来研究需融合绿色化学原则,推动跨学科合作,解决催化剂寿命周期管理与规模化应用挑战,为碳中和战略提供技术支撑。
This paper systematically reviews the progress in the design and application of efficient catalysts for the goal of carbon neutrality. As the key medium for accelerating chemical reactions, catalysts play a core role in core areas such as carbon dioxide reduction (CO22RR) and hydrogen energy production. By optimizing activity, selectivity, stability and durability, they significantly reduce energy consumption and carbon emissions. Metal-based catalysts (such as platinum and copper alloys) improve their performance through nanostructure regulation and composite design, while non-metal-based catalysts (such as nitrogen-doped carbon materials) and biocatalysts show low cost and environmental friendliness. Future research needs to integrate green chemistry principles, promote interdisciplinary cooperation, solve the challenges of catalyst life cycle management and large-scale application, and provide technical support for the carbon neutrality strategy.
[1] Wang, Zhuo, et al. "The role of machine learning in carbon neutrality: Catalyst property prediction, design, and synthesis for carbon dioxide reduction." EScience 3.4 (2023): 100136.
[2] Lu, Chao, Xiaohong Zhang, and Xi Chen. "Advanced materials and technologies toward carbon neutrality." Accounts of Materials Research 3.9 (2022): 913-921.
[3] Yan, Tianxiang, et al. "Multiscale CO2 electrocatalysis to C2+ products: reaction mechanisms, catalyst design, and device fabrication." Chemical Reviews 123.17 (2023): 10530-10583.
[4] Wang, Ligang, Dingsheng Wang, and Yadong Li. "Single‐atom catalysis for carbon neutrality." Carbon Energy 4.6 (2022): 1021-1079.
[5] Chen, Zhijie, et al. "Eco-designed electrocatalysts for water splitting: a path toward carbon neutrality." International Journal of Hydrogen Energy 48.16 (2023): 6288-6307.
[6] Yang, Xiaoxuan, et al. "Achievements, challenges, and perspectives on nitrogen electrochemistry for carbon‐neutral energy technologies." Angewandte Chemie International Edition 62.10 (2023): e202215938.
[7] Zhou, Lingxi, and Ruitao Lv. "Rational catalyst design and interface engineering for electrochemical CO2 reduction to high-valued alcohols." Journal of Energy Chemistry 70 (2022): 310-331.
[8] Caineng, Z. O. U., et al. "Progress, challenge and significance of building a carbon industry system in the context of carbon neutrality strategy." Petroleum Exploration and Development 50.1 (2023): 210-228.
[9] Zhang, Xiaofei, et al. "Enabling heterogeneous catalysis to achieve carbon neutrality: Directional catalytic conversion of CO2 into carboxylic acids." Carbon Energy 6.3 (2024): e362.
[10] Chapman, Andrew, et al. "Achieving a carbon neutral future through advanced functional materials and technologies." Bulletin of the Chemical Society of Japan 95.1 (2022): 73-103.
[11] He, Mingyuan, Yuhan Sun, and Buxing Han. "Green carbon science: efficient carbon resource processing, utilization, and recycling towards carbon neutrality." Angewandte Chemie 134.15 (2022): e202112835.
[12] Zou, Caineng, et al. "Connotation, innovation and vision of “carbon neutrality”." Natural Gas Industry B 8.5 (2021): 523-537.
[13] 徐恒.面向碳中和的分子型催化剂和单原子催化剂结构设计与催化性能[D].天津理工大学,2022.
[14] 王嘉,张元波,苏子键,等."碳中和"背景下高效,低成本减碳脱硝催化剂的制备及其性能研究[C]//第十二届中国金属学会青年学术年会暨首届〝碳中和〞冶金青年科学家沙龙论文集(二).2024.
[15] 唐蜜,刘少华,周红生,等.二氧化碳加氢合成甲醇催化剂研究进展[J].精细与专用化学品, 2024, 32(9):14-18. DOI:10.19482/j.cn11-3237.2024.09.04.
[16] 林翎,李鹏程.发挥能效标准作为碳达峰碳中和目标的催化剂与加速器效应建议[J].中国能源, 2021. DOI:10.3969/j.issn.1003-2355.2021.08.005.
[17] 解兴春,白梅,李应飞,等.高效催化剂的研制助力实现碳达峰碳中和探析[J].环境保护与循环经济, 2022(006): 042. DOI:10.3969/j.issn.1674-1021.2022.06.006.
[18] 张建国.能源服务企业:碳达峰进程中的"催化剂"[J].新理财(公司理财), 2024(8):76-79.
[19] 陈婉.碳达峰碳中和激活绿色金融发展新空间[J].环境经济, 2021, 000(006):P.28-31.